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RESEARCH PRODUCT
Pressure Effect on Spin Crossover in [Fe(phen)2(NCS)2] and [CrI2(depe)2]
Georg LevchenkoP. GütlichB. FitzsimmonsVadim KsenofontovAna B. Gasparsubject
Condensed matter physicsSpin crossoverChemistryHydrostatic pressureSpectrochemical seriesMaterials ChemistrySpin transitionPhysical chemistryElectronic structurePhysical and Theoretical ChemistrySurfaces Coatings and Filmsdescription
In the present article, we discuss the results of investigations of the influence of hydrostatic pressure (up to 1.2 GPa) on the spin transition behavior in [Fe(phen)2(NCS)2] polymorph II and [CrI2(depe)2]. It is demonstrated that pressure effect studies are very helpful in elucidating the mechanism of cooperative dynamic electronic structure phenomena accompanied by significant volume changes. Application of hydrostatic pressure serves as a tool for modifying the ligand field strength in a controlled manner.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2004-05-15 | The Journal of Physical Chemistry B |