6533b7dbfe1ef96bd1270ca9

RESEARCH PRODUCT

Adsorptive Separation of CO2 by a Hydrophobic Carborane-Based Metal-Organic Framework under Humid Conditions

Lei GanEduardo Andres-garciaGuillermo Mínguez EspallargasJosé Giner Planas

subject

Selective gas separationGeneral Materials ScienceHumid conditionsQuímicaMetal−organic frameworksCO2 adsorptionCarboranesHydrophobicBreakthrough

description

We report that the carborane-based metal-organic framework (MOF) mCB-MOF-1 can achieve high adsorptive selectivity for CO2:N2 mixtures. This hydrophobic MOF presenting open metal sites shows high CO2 adsorption capacity and remarkable selectivity values that are maintained even under extremely humid conditions. The comparison of mCB-MOF-1' with MOF-74(Ni) demonstrates the superior performance of the former under challenging moisture operation conditions.

yearjournalcountryeditionlanguage
2023-02-01
10.1021/acsami.2c20373https://hdl.handle.net/10550/85740