6533b7dbfe1ef96bd1270d97

RESEARCH PRODUCT

IR Bandshapes of Intramolecularly H-Bonded Systems II. 2,4-Dibromophenol

subject

intramolecular H-bondscorrelation functionsvibrational dephasingIR bandshapes

description

A detailed quantitative study of the IR bandshape of the ϑs(OH) vibration of 2,4-dibromophenol in a series of solvents is presented.A distinct dependence of band positions, shape parameters, correlation functions and correlation times from solvent polarity has been found.The contribution of various shaping mechanisms to the profile is discussed.

10.1524/zpch.1984.141.2.159https://doi.org/10.1524/zpch.1984.141.2.159