6533b7dcfe1ef96bd1271f1e

RESEARCH PRODUCT

[5,10,15,20-Tetrakis(4-tert-butylphenyl)-porphyrinato-κ4N] zinc(II) toluene solvate

Krzysztof EjsmontGiuseppe MeleRudolf SłotaAndrzej A. DomańskiRoberta Del Sole

subject

chemistry.chemical_compoundCrystallographychemistryStereochemistryClathrate hydratechemistry.chemical_elementGeneral Materials ScienceGeneral ChemistryZincCondensed Matter PhysicsToluenePorphyrin

description

The structure of the title compound, [Zn(C60H60N4)]·C7H8, represents a typical clathrate containing a host mol­ecule of [5,10,15,20-tetra­kis(4-tert-butyl­phen­yl)­porphyrin­ato]­zinc(II) and a toluene guest mol­ecule. The Zn atom occupies an inversion center and exhibits ideal square-planar coordination, while the porphyrin group remains perfectly flat. The toluene mol­ecule lies on an inversion center and is disordered.

yearjournalcountryeditionlanguage
2007-09-21Acta Crystallographica Section E: Crystallographic Communications
10.1107/s1600536807045953http://scripts.iucr.org/cgi-bin/paper?S1600536807045953