6533b7dcfe1ef96bd12720e3
RESEARCH PRODUCT
Synthesis and Characterization of a Soluble Bimetallic Oxalate-Based Bidimensional Magnet: [K(18-crown-6)]3[Mn3(H2O)4{Cr(ox)3}3]
Carlos Martí-gastaldoEugenio CoronadoJosé Ramón Galán-mascaróssubject
chemistry.chemical_classificationStereochemistry18-Crown-6OxalateCharacterization (materials science)Inorganic Chemistrychemistry.chemical_compoundCrystallographychemistryFerromagnetismMagnetPhysical and Theoretical ChemistryBimetallic stripCrown etherdescription
The "templating" K crown ether cation allows for the preparation of soluble layered oxalate-based bimetallic magnets, as in [K(18-crown-6]3{Mn3(H2O)4[Cr(ox)3]3}, with an unprecedented bidimensional polymeric anionic network that involves both oxalato bridges and H bonds. As in other 2D oxalate-bridged compounds, the compound behaves as a soft ferromagnet, with the onset of magnetic ordering occurring at 3.3 K.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2006-02-28 | Inorganic Chemistry |