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RESEARCH PRODUCT
Synthesis and Characterization of Fluorescent, Low-Symmetry Triphenylene Discotic Liquid Crystals: Tailoring of Mesomorphic and Optical Properties
Helmut RingsdorfJames A. RegoSandeep Kumarsubject
ChemistryGeneral Chemical EngineeringDiscotic liquid crystalMesophaseTriphenyleneGeneral ChemistryFluorescenceDipoleCrystallographychemistry.chemical_compoundLiquid crystalMaterials ChemistrySurface modificationOrganic chemistryColumnar phasedescription
A series of monofunctionalized triphenylene-based discotic liquid crystals were synthesized starting from 2-hydroxy-3,6,7,10,11-pentakis(pentyloxy)triphenylene. These compounds are unique in that they possess a single electron-withdrawing group (and consequently a large dipole moment) connected directly to the polyaromatic core. All of the new liquid crystals show a significantly broader range of mesogenicity relative to the parent compound 2,3,6,7,10,11-hexakis(pentyloxy)triphenylene. Moreover, some of the new mesogens exhibit a more ordered mesophase relative to the hexagonal columnar phase (Dh) at lower temperatures. Monofunctionalization of the triphenylene core has a dramatic effect on the photophysical properties of the mesogens such as the color and efficiency of fluorescence.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1996-01-01 | Chemistry of Materials |