6533b7dcfe1ef96bd127357d
RESEARCH PRODUCT
Crystal structure and Hirshfeld surface analysis of (Z)-4-chloro-N′-(4-oxothiazolidin-2-ylidene)benzenesulfonohydrazide monohydrate
Sabine ForoB. Thimme GowdaNikhila Paisubject
thiazole derivativecrystal structureCrystallography010405 organic chemistryHydrogen bondBent molecular geometryGeneral ChemistryCrystal structure010403 inorganic & nuclear chemistryCondensed Matter PhysicsHydrazide01 natural sciences0104 chemical sciencesCrystalchemistry.chemical_compoundCrystallographychemistryQD901-999hydrogen bondsMoietyHirshfeld surface analysisGeneral Materials SciencePhysics::Chemical PhysicsBenzeneDerivative (chemistry)description
The asymmetric unit of the title thiazole derivative containing a sulfonylhydrazinic moiety, C9H8ClN3O3S2·H2O, consists of two independent molecules and two water molecules. The central parts of the molecules are twisted as both the molecules are bent at both the S and N atoms. In the crystal, N—H...N, N—H...O, C—H...O and O—H...O hydrogen-bonding interactions connect the molecules, forming layers parallel to the ab plane. Two-dimensional fingerprint plots associated with the Hirshfeld surface show that the largest contributions to the crystal packing come from O...H/H...O (32.9%) and H...H (22.6%) interactions.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2018-11-01 | Acta Crystallographica Section E: Crystallographic Communications |