Electrochemical and spectroscopic characterization of cobalt and zinc diaza‐18‐crown‐6 porphyrins and of a zinc dioxocyclam porphyrin

6533b7dcfe1ef96bd127357f

RESEARCH PRODUCT

Electrochemical and spectroscopic characterization of cobalt and zinc diaza‐18‐crown‐6 porphyrins and of a zinc dioxocyclam porphyrin

Caroline Comte Jianguo Shao Karl M. Kadish Roger Guilard Claude P. Gros Zhongping Ou

subject

Metal ions in aqueous solution 18-Crown-6 Inorganic chemistry chemistry.chemical_element General Chemistry Zinc Electrochemistry Mass spectrometry Porphyrin chemistry.chemical_compound chemistry Polymer chemistry Fourier transform infrared spectroscopy Cobalt

description

The synthesis and electrochemical characterization of ‘crowned’ and ‘dioxocyclam’ metalloporphyrins containing Co(II) or Zn(II) metal ions is presented. Each complex is also characterized by mass spectrometry in addition to a variety of spectroscopic techniques (UV-vis, FTIR, ESR (in the case of Co(II)) and 1H and 13CNMR spectroscopy).

year	journal	country	edition	language
2000-10-13	Journal of Porphyrins and Phthalocyanines

https://doi.org/10.1002/1099-1409(200011)4:7<639::aid-jpp305>3.0.co;2-#

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