6533b7ddfe1ef96bd1273e51

RESEARCH PRODUCT

Probing the guest-binding preference of three structurally similar and conformationally adaptive macrocycles.

Hongxin ChaiFangfang PanLiu-pan YangZhi-sheng PanKari RissanenShan HeWei Jiang

subject

010405 organic chemistryChemistryStereochemistryMetals and AlloysGeneral Chemistry010402 general chemistry01 natural sciencesCatalysisPreference0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsMaterials ChemistryCeramics and Composites

description

A hybrid macrocycle was synthesized by combining the repeat units in oxatub[4]arene and zorb[4]arene, and its recognition behavior and conformational analysis were studied. Three structurally similar and conformationally adaptive macrocycles show different guest-binding selectivities and preferences even in a complex mixture containing three macrocycles and three guests.

10.1039/c9cc03341fhttps://pubmed.ncbi.nlm.nih.gov/31210219