6533b7ddfe1ef96bd1274190
RESEARCH PRODUCT
Stable spirocyclic neutral radicals: aluminum and gallium boraamidinates
Tristram ChiversDana EislerChantall FedorchukGabriele SchatteHeikki TuononenRené Boerésubject
stable radicalsboraamidinaatitboraamidinatespysyvät radikaalitdescription
Stable dark red (M = Al) or dark green (M = Ga) neutral radicals {[PhB(μ-NtBu)2]2M}˙ are obtained by the oxidation of their corresponding anions with iodine, and EPR spectra supported by DFT calculations show that the spin density is equally delocalized over all four nitrogen atoms in these spiroconjugated systems. peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2005-01-01 |