6533b7ddfe1ef96bd1274828
RESEARCH PRODUCT
Templated synthesis of a large and flexible covalent porphyrinic cage bearing orthogonal recognition sites.
Julien TaeschValérie HeitzKari RissanenFilip Topićsubject
PorphyrinsSymmetric structureStereochemistryMolecular Conformationchemistry.chemical_elementZincDABCOCrystallography X-RayLigandsCatalysisMolecular conformationPiperazineslaw.inventionchemistry.chemical_compoundlawPolymer chemistryMaterials Chemistryta116Bearing (mechanical)Olefin metathesisMetals and AlloysGeneral ChemistrySurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsZincchemistryCovalent bondCeramics and CompositesCagedescription
A large covalent cage incorporating two porphyrins attached by four long and flexible polyether chains each bearing two 3-pyridyl ligands was synthesized from a DABCO-templated olefin metathesis reaction. The X-ray structure of the cage with the DABCO coordinated inside the cavity to the two zinc(II) porphyrins reveals a highly symmetric structure.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-04-21 | Chemical communications (Cambridge, England) |