6533b7ddfe1ef96bd1274961

RESEARCH PRODUCT

Synthesis, crystal structure and magnetic properties of a novel heterobimetallic rhenium(IV)-dysprosium(III) chain.

Raúl ChiozzoneFrancesc LloretCarolina PejoRicardo GonzálezNivaldo L. SpezialiGuilherme P. GuedesMaria G. F. VazMiguel JulveMiguel A. Novak

subject

Magnetic measurementsChemistryOrganic ChemistryRelaxation (NMR)Inorganic chemistrychemistry.chemical_elementGeneral ChemistryFrequency dependenceCrystal structureRheniumCatalysisMagnetizationCrystallographyChain (algebraic topology)Dysprosium

description

The use of the mononuclear rhenium(IV) precursor [ReBr5 (H2 pydc)](-) (H2 pydc=3,5-pyridinedicarboxylic acid) as a metalloligand towards dysprosium(III) afforded the first heterobimetallic Re(IV) -Dy(III) complex. Crystal structures and static and dynamic magnetic properties of both rhenium-containing species are reported herein. The 5d-4f compound shows an extended 1D structure and the AC magnetic measurements reveal frequency dependence at low temperature suggesting slow relaxation of the magnetization.

yearjournalcountryeditionlanguage
2015-01-14Chemistry (Weinheim an der Bergstrasse, Germany)
10.1002/chem.201500168https://pubmed.ncbi.nlm.nih.gov/25916407