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RESEARCH PRODUCT
Thermal 1,6-Electrocyclization Reactions of Acceptor-Substituted 2,3-Divinyl-1H-indoles Yielding Functionalized Carbazoles
Reinhard AdamUlf Pindursubject
Electrocyclic reactionBicyclic moleculeChemistryOrganic ChemistryBiochemistryAcceptorCatalysisInorganic ChemistryChemical couplingDrug DiscoveryWittig reactionOrganic chemistryThermal reactionPhysical and Theoretical Chemistrydescription
Three new synthetic procedures for and thermal 1,6-electrocyclizations of acceptor-substituted 2,3-divinyl-1H-indoles leading to functionalizing carbazoles are described. The scope and limitations as well as some mechanistic aspects of the methodologies are discussed. The key strategies employed include Pd(II)-catalyzed coupling and Wittig procedures.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1990-06-20 | Helvetica Chimica Acta |