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RESEARCH PRODUCT
Controlled Self-Assembly of Electron Donor Nanotubes
Enrique OrtíNazario MartínEmilio M. PérezPedro M. ViruelaJuan Luis LópezRafael Viruelasubject
Solventchemistry.chemical_compoundchemistryTtf derivativesChemical engineeringHydrogen bondOrganic ChemistryStackingNanotechnologyElectron donorSelf-assemblyPhysical and Theoretical ChemistryBiochemistrydescription
We employ a combination of urea-urea hydrogen bonds and pi-pi stacking interactions to obtain soluble self-assembled nanotubes decorated with electron-donor TTF derivatives on the periphery. We have investigated the structure and stability of the nanotubes with a combination of experiments and high-level DFT calculations. We also demonstrate that the association process can be controlled by changes in the hydrogen-bonding ability of the solvent and electrochemically.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2009-01-01 | Organic Letters |