6533b7ddfe1ef96bd1275408
RESEARCH PRODUCT
Slow magnetic relaxation in a hydrogen-bonded 2D array of mononuclear dysprosium(III) oxamates.
Miguel JulveEmilio PardoDonatella ArmentanoJulia VallejoGiovanni De MunnoFrancesc LloretFrancisco R. Fortea-pérezsubject
chemistry.chemical_classificationLanthanideModels MolecularOxamic AcidHydrogenInorganic chemistrychemistry.chemical_elementHydrogen BondingPolymerIonInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryCoordination ComplexesMagnetDysprosiumDysprosiumMagnetsPhysical and Theoretical ChemistryBifunctionalTopology (chemistry)description
The reaction of N-(2,6-dimethylphenyl)oxamic acid with dysprosium(III) ions in a controlled basic media afforded the first example of a mononuclear lanthanide oxamate complex exhibiting a field-induced slow magnetic relaxation behavior typical of single-ion magnets (SIMs). The hydrogen-bond-mediated self-assembly of this new bifunctional dysprosium(III) SIM in the solid state provides a unique example of 2D hydrogen-bonded polymer with a herringbone net topology.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-04-20 | Inorganic chemistry |