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RESEARCH PRODUCT
Slow relaxation of the magnetization in a 4,2-wavelike Fe(III)2Co(II) heterobimetallic chain.
Miguel JulveLuminita Marilena TomaFrancesc LloretCatalina Ruiz-pérezsubject
Inorganic ChemistryCrystallographyMagnetizationCondensed matter physicschemistryFerromagnetismChain (algebraic topology)Relaxation (NMR)chemistry.chemical_elementPhysical and Theoretical ChemistryCobaltIondescription
The reaction of the low-spin iron(III) complex [Fe(dmbpy)(CN)(4)](-) (1) with fully solvated cobalt(II) ions affords the cyanide-bridged heterobimetallic chain {[Fe(III)(dmbpy)(CN)(4)](2)Co(II)(H(2)O)(2)}(n) · 4nH(2)O (2), which exhibits intrachain ferromagnetic coupling and double slow relaxation of the magnetization.
year | journal | country | edition | language |
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2012-01-26 | Inorganic chemistry |