6533b7ddfe1ef96bd1275466

RESEARCH PRODUCT

Slow relaxation of the magnetization in a 4,2-wavelike Fe(III)2Co(II) heterobimetallic chain.

Miguel JulveLuminita Marilena TomaFrancesc LloretCatalina Ruiz-pérez

subject

Inorganic ChemistryCrystallographyMagnetizationCondensed matter physicschemistryFerromagnetismChain (algebraic topology)Relaxation (NMR)chemistry.chemical_elementPhysical and Theoretical ChemistryCobaltIon

description

The reaction of the low-spin iron(III) complex [Fe(dmbpy)(CN)(4)](-) (1) with fully solvated cobalt(II) ions affords the cyanide-bridged heterobimetallic chain {[Fe(III)(dmbpy)(CN)(4)](2)Co(II)(H(2)O)(2)}(n) · 4nH(2)O (2), which exhibits intrachain ferromagnetic coupling and double slow relaxation of the magnetization.

10.1021/ic202410thttps://pubmed.ncbi.nlm.nih.gov/22272773