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RESEARCH PRODUCT

A new synthetic route to tribenzo[a,e,i][12]annulenes

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description

Abstract The tribenzo[a,e,i][12]annulene 10 and the corresponding twofold annulene 14 were prepared on synthetic routes which first led from suitably functionalised starting compounds (2, 11) to the 1,2-distyryl- and 1,2,3,4-tetrastyrylbenzene derivatives 9 and 13 with two and four formyl groups, respectively. The cyclisation to 10 and 14 was achieved by applying the McMurry reaction. The extended ring system of compound 14 represents a discotic mesogen. The generation of liquid crystals was obtained with eight hexyloxy chains on the periphery.