6533b7defe1ef96bd1275b41

RESEARCH PRODUCT

Trifluoracetylierung von aminosäureestern und dipeptidestern mit N-trifluoracetyl-polyamid 66.

Rolf C. SchulzHelmut W. Tesch

subject

chemistry.chemical_classificationchemistry.chemical_compoundDipeptideChemistryReagentOrganic chemistryGas chromatographyAmino acid

description

N-Trifluoroacetyl-Polyamid 66 (1) is used for the trifluoroacetylation of amino acid- and dipeptide esters. Advantages and limitations of the polymeric reagent compared with low molecular trifluoroacetylating reagents are discussed. A mixture of amino acid methyl esters can be converted by 1 to the N-trifluoroacetyl derivatives, which are separated and identified by gas chromatography.

https://doi.org/10.1002/macp.1981.021821106