6533b7defe1ef96bd1275b53

RESEARCH PRODUCT

ChemInform Abstract: A Novel Synthesis of Chain-Extended Amino Sugar Derivatives Through Aza-Cope Rearrangement of N-Galactosyl-N-homoallylamines.

Horst KunzSandrine Deloisy

subject

chemistry.chemical_classificationAmino sugarChain (algebraic topology)ChemistryStereochemistryYield (chemistry)Aza-Cope rearrangementStereoselectivityGeneral Medicine

description

Abstract Chain-extended amino sugars are synthesized via stereocontrolled Lewis acid-catalyzed aza-Cope rearrangement of N-glycosyl homoallylamines in high yield and stereoselectivity.

https://doi.org/10.1002/chin.199821200