6533b7defe1ef96bd1275f40

RESEARCH PRODUCT

Formation of an interlocked double-chain from an organic-inorganic [2]rotaxane.

Christopher A. MurynIñigo J. Vitorica-yrezabalRichard E. P. WinpennyJesús Ferrando-soriaJesús Ferrando-soriaFloriana TunaDeepak AsthanaGrigore A. TimcoAntonio FernandezAntonio Fernandez

subject

Rotaxane010405 organic chemistryChemistryMetals and AlloysGeneral Chemistry010402 general chemistry01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsDouble chainMetalchemistry.chemical_compoundTheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITYvisual_artPolymer chemistryOrganic inorganicMaterials ChemistryCeramics and Compositesvisual_art.visual_art_mediumCarboxylateDaisy chain

description

Here we show that a structure containing a polymeric interlocking daisy chain is obtained from the reaction of an inorganic–organic [2]rotaxane [HB{CrIII7NiII(μ-F)8(O2CtBu)16}], where B is an organic thread terminated with a bi-pyridyl unit, with an oxo-centered metal carboxylate triangle [FeIII2CoII(μ3-O)(O2CtBu)6(HO2CtBu)3].

yearjournalcountryeditionlanguage
2019-02-20Chemical communications (Cambridge, England)
10.1039/c8cc09339chttps://pubmed.ncbi.nlm.nih.gov/30778447