6533b7defe1ef96bd127656e

RESEARCH PRODUCT

Palladium–Polypyrrole Nanoparticles-Catalyzed Sonogashira Coupling

Mikhail A. VorotyntsevMikhail A. VorotyntsevMikhail A. VorotyntsevOleg M. NikitinTatiana V. MagdesievaEkaterina V. ZolotukhinEkaterina V. ZolotukhinEkaterina V. ZolotukhinVeronika A. Zinovieva

subject

chemistry.chemical_compoundchemistrychemistry.chemical_elementSonogashira couplingPalladium nanoparticlesGeneral ChemistryPolypyrrolePhotochemistryRedoxPolypyrrole nanoparticlesPalladiumCatalysisPyrrole

description

Abstract Palladium nanoparticles were encapsulated into polypyrrole globules via one-step one-pot redox reaction between tetraamminepal- ladium(ii) dichloride and pyrrole in water. Such a material is an active catalyst for the Sonogashira coupling of iodo- and bromo- arenes.

https://doi.org/10.1016/j.mencom.2012.11.008