Synthesis, characterization and ethylene polymerization by metallasilsesquioxane

6533b7defe1ef96bd1276630

RESEARCH PRODUCT

Synthesis, characterization and ethylene polymerization by metallasilsesquioxane

Marzena Białek Girish Mehta Akshay Mehta Parimal A. Parikh Gopal L. Tembe

subject

Wax Materials science Ethylene Polymers and Plastics Dispersity Polyethylene Silsesquioxane Catalysis chemistry.chemical_compound Surface coating chemistry Polymerization visual_art Polymer chemistry visual_art.visual_art_medium

description

Soluble complexes of group (IV) metallocenes anchored on a substituted polyhedral oligomeric silsesquioxane trisilanol support were prepared and characterized. These catalyst precursors formulated as [M(O^O^O)X] are found to be active in polymerization of ethylene at high temperature in combination with ethylaluminum sesquichloride (Et3Al2Cl3, EASC) as co-catalyst. The polyethylene obtained by these catalysts is linear, crystalline and displays narrow dispersity. The unique low molecular weight PE formed in this reaction exhibits properties comparable to commercial micronized PE waxes that have potential industrial applications in surface coating and ink formulations. Copyright © 2013 John Wiley & Sons, Ltd.

year	journal	country	edition	language
2013-02-12	Polymers for Advanced Technologies

https://doi.org/10.1002/pat.3100

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