Counterion-Mediated Crossing of the Cyanine Limit in Crystals and Fluid Solution: Bond Length Alternation and Spectral Broadening Unveiled by Quantum Chemistry

6533b81ffe1ef96bd1277321

RESEARCH PRODUCT

Counterion-Mediated Crossing of the Cyanine Limit in Crystals and Fluid Solution: Bond Length Alternation and Spectral Broadening Unveiled by Quantum Chemistry

Johannes Gierschner Juan Carlos Roldao Morteza Eskandari Begoña Milián-medina Javier Cerezo

subject

chemistry.chemical_classification Physics::Biological Physics Quantitative Biology::Biomolecules Absorption spectroscopy General Chemistry 010402 general chemistry 01 natural sciences Biochemistry Quantum chemistry Catalysis 0104 chemical sciences Condensed Matter::Soft Condensed Matter Solvent chemistry.chemical_compound Colloid and Surface Chemistry Fluid solution chemistry Chemical physics Physics::Chemical Physics Counterion Cyanine Doppler broadening Dichloromethane

description

Absorption spectra of cyanine⊕·Br⊖ salts show a remarkable solvent dependence in non/polar solvents, exhibiting narrow, sharp band shapes in dichloromethane but broad features in toluene; this chan...

year	journal	country	edition	language
2020-01-01

10.1021/jacs.9b10686 http://hdl.handle.net/20.500.12614/1492

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