6533b81ffe1ef96bd12779c7
RESEARCH PRODUCT
Introduction of unsaturated segments in the bridge of metacyclophanes
Derong CaoHerbert MeierHeinz Kolshornsubject
StereochemistryChemistryOrganic ChemistryDrug DiscoveryNanotechnologyTriple bondBiochemistryIsomerizationBridge (interpersonal)description
Abstract The cyclophanes 2a,b, which contain a triple bond in the meta-bridge, were transformed to the allenes 3a,b by the action of bases or acids. A further isomerization yielded the dienes 4a,b with ( E,Z )- or ( Z,Z )-configuration.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1995-09-01 | Tetrahedron Letters |