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RESEARCH PRODUCT

Diphenoxo-Bridged NiIILnIII Dinuclear Complexes as Platforms for Heterotrimetallic (LnIIINiII)2RuIII Systems with a High-Magnetic-Moment Ground State: Synthesis, Structure, and Magnetic Properties

Reijo SillanpääEnrique ColacioJosé RuizMikko M. HänninenAntonio J. MotaMaria A. Palacios

subject

Inorganic ChemistryCrystallographyMagnetic momentFerromagnetismChemistryStereochemistryStructure (category theory)Physical and Theoretical ChemistryGround stateta116

description

The first examples of pentanuclear heterotrimetallic [(LnNi)(2)Ru] [Ln(3+) = Gd (1) and Dy (2)] complexes were prepared and magnetostructurally characterized. They exhibit ferromagnetic interactions, leading to a high-magnetic-moment ground state.

https://doi.org/10.1021/ic3008443