6533b81ffe1ef96bd1277d59
RESEARCH PRODUCT
Bis[cyclic (alkyl)(amino)carbene] isomers: Stable trans -bis(CAAC) versus facile olefin formation for cis -bis(CAAC)
Braulio M. Puerta LombardiEthan R. PezoulasRoope A. SuvinenAlexander HarrisonZachary S. DubrawskiBenjamin S. GelfandHeikki M. TuononenRoland Roeslersubject
Materials ChemistryMetals and AlloysCeramics and CompositesGeneral ChemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialsdescription
A trans-bis(CAAC) was isolated and shown to be a ditopic ligand for rhodium and iridium. The cis-isomer is unstable towards intramolecular CC-bond formation, however, its formal insertion products into the bonds of H2O and NH3 were identified.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2022-01-01 | Chemical Communications |