6533b81ffe1ef96bd1278f01
RESEARCH PRODUCT
Enantioselective sensing of dicarboxylates. Influence of the stoichiometry of the complexes on the sensing mechanism
Manuel ColeraUrsula LlaosaAna M. CosteroAna M. CosteroSalvador GilSalvador GilMargarita ParraMargarita Parrasubject
CyclohexaneChemistryStereochemistryorganic chemicalsOrganic ChemistryEnantioselective synthesisFluorescenceCombinatorial chemistryCatalysisInorganic Chemistrychemistry.chemical_compoundThioureaMoietyheterocyclic compoundsPhysical and Theoretical ChemistryStoichiometrydescription
Two new cyclohexane-based thiourea chiral ligands have been synthesized in their enantiomerically pure forms. Both the ability of these ligands in the complexation of chiral dicarboxylates and their sensing properties have been studied. The influence of the stoichiometry of the formed complexes on the fluorescent properties of the systems has been established. The effect of additional substitution in the cyclohexyl moiety was considered by comparing the properties of the newly prepared ligands with those of similar compounds previously described.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2009-07-01 | Tetrahedron: Asymmetry |