Tristriazolotriazines with π-Conjugated Segments: Star-Shaped Fluorophors and Discotic Liquid Crystals

6533b820fe1ef96bd1279869

RESEARCH PRODUCT

Tristriazolotriazines with π-Conjugated Segments: Star-Shaped Fluorophors and Discotic Liquid Crystals

Thorsten Rieth Heiner Detert Dorothee Borchmann Stefan Glang

subject

chemistry.chemical_compound Materials science chemistry Phenylene Discotic liquid crystal Cyanuric chloride Solvatochromism Halochromism Side chain Columnar phase Photochemistry Thermotropic crystal

description

C3-symmetrical tristriazolotriazines substituted with phenylene rings carrying lateral flexible alkoxy side chains were prepared via condensation/ring transformation of cyanuric chloride and tetrazoles. These star-shaped, planar compounds can form broad thermotropic mesophases. Due to the extensive π-conjugation, these compounds are highly emissive and the octupolar donor-acceptor electronic structure results in non-linear optical properties like solvatochromism. Brønstedt acids provoke halochromism of the absorption and of the fluorescence.

year	journal	country	edition	language
2012-09-11	Advances in Science and Technology

https://doi.org/10.4028/www.scientific.net/ast.77.118

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