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RESEARCH PRODUCT

ChemInform Abstract: 4-Fluoroanilines: Synthesis and Decomposition.

Erkki KolehmainenRyszard GawineckiBorys OsmialowskiAnna Zakrzewska

subject

NMR spectra databasechemistry.chemical_compoundChloroformchemistryComputational chemistryChemical shiftOrganic chemistryGeneral MedicineDecompositionPyrrole derivatives

description

Abstract Fourteen N- and/or 2-substituted 4-fluoroanilines were prepared (the series includes N–C2-bridged compounds). Some of them were found to be thermally unstable when dissolved in chloroform. Both 19 F NMR spectra and comparison of GIAO-DFT calculated and experimental 13 C chemical shifts were used to suggest decomposition products of 4-fluoroanilines.

https://doi.org/10.1002/chin.200220029