cis-[Bis(diphenylphosphino)ethane-κ2P,P′]dichlororuthenium(II) dichloromethane disolvate

6533b820fe1ef96bd1279ad1

RESEARCH PRODUCT

cis-[Bis(diphenylphosphino)ethane-κ2P,P′]dichlororuthenium(II) dichloromethane disolvate

Kari Rissanen João Rodrigues João Figueira Luca Russo

subject

Chemistry Stereochemistry chemistry.chemical_element General Chemistry .Condensed Matter Physics Chloride Medicinal chemistry Ruthenium chemistry.chemical_compound Faculdade de Ciências Exatas e da Engenharia medicine General Materials Science Cis–trans isomerism medicine.drug Dichloromethane cis-[Bis(diphenylphosphino)ethane-j2P P000]dichlororuthenium(II) dichloromethane disolvate

description

The title compound, cis-[RuCl2(C26H24P2)2]·2CH2Cl2, was obtained as an unexpected product from our attempts to prepare new ruthenium molecular wires using organic bridging ligands. Three solvates and a solvent-free structure of the isomeric complex with the chloride anions in a trans geometry have already been reported, while the cis isomer has been described only in solution studies prior to this work.

year	journal	country	edition	language
2006-04-29

10.1107/s1600536806015005

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