6533b820fe1ef96bd127a28c

RESEARCH PRODUCT

Assemblies of semiconductor quantum dots and light-harvesting-complex II

Wolfgang ErkerRenguo XieHarald PaulsenThomas BaschéStephanie BoggaschGötz Grundmann

subject

Quenching (fluorescence)ChemistryEnergy transfertechnology industry and agricultureBiophysicsNanotechnologyGeneral Chemistryequipment and suppliesCondensed Matter PhysicsBiochemistryFluorescenceAtomic and Molecular Physics and OpticsLight-harvesting complexSemiconductor quantum dotsQuantum dotChemical physicsHybrid materialLight harvesting complex II

description

Abstract A novel hybrid system composed of fluorescent core/shell semiconductor quantum dots and the light harvesting complex II (LHCIIb), a membrane protein of higher plants, has been assembled. Experiments with different mutants show that hybrid formation can be mediated by a C-terminal His 6 tag attached to the protein as well as by positive charges of the first N-terminal amino acids of LHCIIb. Quenching of the quantum dot fluorescence upon binding of LHCIIb was partially attributed to energy transfer from the quantum dots to LHCIIb.

https://doi.org/10.1016/j.jlumin.2009.12.002