6533b820fe1ef96bd127a316

RESEARCH PRODUCT

Tripoxyrollin, a New Epoxy Acetogenin from the Seeds ofRollinia membranacea1

André CavéBruno FigadèreSevser SahpazJairo SaezReynald HocquemillerDiego Cortes

subject

Rollinia membranaceabiologyStereochemistryIsodesacetyluvaricinEpoxybiology.organism_classificationchemistry.chemical_compoundchemistryAnnonaceaeBiomimetic synthesisvisual_artAcetogeninvisual_art.visual_art_mediumMolecular MedicineOrganic chemistrySpectral data

description

Abstract A new epoxy acetogenin, tripoxyrollin (1), has been isolated from the seeds of the Colombian Annonaceae, Rollinia membranacea. Its structure was elucidated on the basis of spectral data. Biomimetic synthesis of isodesacetyluvaricin (2) from tripoxyrollin (1) suggests its key role in the biogenesis of the adjacent bis-tetrahydrofuran acetogenins.

https://doi.org/10.1080/10575639308043826