6533b821fe1ef96bd127ad96

RESEARCH PRODUCT

Photovoltaic effect in bulk heterojunction system with glass forming indandione derivative DMABI-6Ph

Janis LatvelsKaspars PudzsAivars VembrisDagnija BlumbergaRaitis Grzibovskis

subject

chemistry.chemical_classificationglass forming structureFullereneMaterials scienceOrganic solar cellOpen-circuit voltage020209 energybulk heterojunction02 engineering and technologyPolymerPhotovoltaic effect021001 nanoscience & nanotechnology7. Clean energyPolymer solar cellpower conversion efficiencyAmorphous solidchemistryChemical engineeringElectron affinity:NATURAL SCIENCES:Physics [Research Subject Categories]0202 electrical engineering electronic engineering information engineeringenergy levels0210 nano-technologyindandione group

description

The aim of the work is to evaluate possible use of 2-[[4-(bis(2-trityloxyethyl)amino)phenyl]methylene]indane-1,3-dione (DMABI-6Ph) as light absorbing material for solar cells. DMABI-6Ph is a perspective material due to its good photoelectrical, thermal and chemical properties. The main advantage of DMABI-6Ph is its ability to form amorphous films by wet-casting methods thus allowing using the compound in organic solar cells made from solution. For now most popular materials for solution processable solar cells are polymer P3HT and fullerene derivative PCBM, but lot of investigations are in the field of new low molecular weight materials to replace the polymer. Photoelectrical measurements were made to determine molecule ionization and electron affinity levels of DMABI-6Ph. Difference of 2.06 eV between DMABI-6Ph ionization level and PCBM affinity level was obtained. Accordingly open circuit voltage of system DMABI-6Ph:PCBM was measured up to 0.78 V. The best power conversation efficiency was 0.11 % for the DMABI-6Ph:PCBM mass fraction 2:1. Limiting factor for high efficiency could be low charge carrier mobility which can be increase by additional DMABI-6Ph modification.

10.1016/j.egypro.2018.07.073http://dx.doi.org/10.1016/j.egypro.2018.07.073