Oxidation of alcohols to carbonyl compounds with CrO3.SiO2 in supercritical carbon dioxide.

6533b821fe1ef96bd127afab

RESEARCH PRODUCT

Oxidation of alcohols to carbonyl compounds with CrO3.SiO2 in supercritical carbon dioxide.

María Elena González-núñez Rafael Acerete Rossella Mello Andrea Olmos Gregorio Asensio

subject

chemistry.chemical_classification Supercritical water oxidation Chromium trioxide Primary (chemistry)Supercritical carbon dioxide Organic Chemistry Inorganic chemistry chemistry.chemical_element Alcohol General Medicine chemistry.chemical_compound Chromium chemistry Alcohol oxidation Reagent Organic chemistry Bridged compounds

description

Supercritical carbon dioxide (scCO2) is an effective reaction medium to perform the oxidation of primary and secondary aliphatic alcohols to the corresponding carbonyl compounds with chromium trioxide supported on silica. These reactions were performed by flowing a solution of the alcohol in scCO2 through a column containing the supported reagent and recovering the product by depressurization. This method avoids the use of organic solvents and the contamination of the products with chromium species.

year	journal	country	edition	language
2006-06-20	The Journal of organic chemistry

10.1021/jo052137j https://pubmed.ncbi.nlm.nih.gov/16438518

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