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RESEARCH PRODUCT
Asymmetric [N–I–N]+ halonium complexes
Giorgia FioriniJas S. WardAntonio FronteraKari Rissanensubject
CrystallographyChemistryMaterials ChemistryMetals and AlloysCeramics and CompositesHalonium ionGeneral ChemistryNuclear magnetic resonance spectroscopySingle crystalCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialsdescription
The first asymmetric halogen-bonded iodonium complexes [I(py)(4-DMAP)]PF6 (2c) and [I(py)(4-Etpy)]PF6 (2e) were prepared via [N–Ag–N]+ → [N–I–N]+ cation exchange of their analogous 2-coordinate silver complexes. The complexes were characterised by 1H and 1H–15N HMBC NMR spectroscopy, and single crystal X-ray crystallography.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2020-01-01 | Chemical Communications |