6533b821fe1ef96bd127b76c
RESEARCH PRODUCT
Synthesis, solution and electrochemical behaviour of new aza-crown ethers derived from biphenyl
Elena MonrabalTeresa PardoJuan SotoCecilia AndreuMiguel E. Padilla-tostaAna M. CosteroJosé María AmigóRamón Martínez-máñezLuis E. Ochandosubject
Biphenylchemistry.chemical_compoundchemistryTransition metalLigandPolymer chemistryPotentiometric titrationInorganic chemistryGeneral ChemistryCrystal structureElectrochemistrydescription
Macrocyclic ligands L1–L4 containing biphenyl units have been synthesized. Potentiometric and voltametric studies in the presence and the absence of transition metal cations have been carried out. The relationship between the conformation of the ligand and oxidation states has been also considered. The crystal structure of [HgL2(CN)2]·2Hg(CN)2 has been elucidated by X-ray diffraction techniques.
year | journal | country | edition | language |
---|---|---|---|---|
2000-01-01 | Journal of the Chemical Society, Dalton Transactions |