Gold(iii) tetraarylporphyrin amino acid derivatives: ligand or metal centred redox chemistry?

6533b821fe1ef96bd127b8be

RESEARCH PRODUCT

Gold(iii) tetraarylporphyrin amino acid derivatives: ligand or metal centred redox chemistry?

Sebastian Preiß Anica Wünsche Von Leupoldt Katja Heinze Jascha Melomedov

subject

chemistry.chemical_classification Valence (chemistry)010405 organic chemistry General Chemistry 010402 general chemistry Photochemistry 01 natural sciences Porphyrin 0104 chemical sciences chemistry.chemical_compound Electron transfer Chemistry chemistry Valence isomer Hexafluorophosphate Density functional theory Electron configuration Counterion

description

EPR spectroscopy and DFT calculations show that the site of reduction of porphyrinato gold(iii) complexes depends on the counterions X, the meso substituents R and the solvent.

year	journal	country	edition	language
2015-09-11	Chemical science

10.1039/c5sc03429a https://pubmed.ncbi.nlm.nih.gov/29896349

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