6533b821fe1ef96bd127bab9
RESEARCH PRODUCT
Paramagnetic aluminium β-diketiminate
Roland RoeslerJani O. MoilanenJavier Borau-garciaHeikki M. Tuononensubject
ChemistryLigandInorganic chemistryMetals and AlloysGeneral ChemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialslaw.inventionParamagnetismCrystallographyUnpaired electronlawGroup (periodic table)Materials ChemistryCeramics and CompositesElectron paramagnetic resonanceta116description
The β-diketiminate ligand framework is shown to undergo reduction to form a neutral main group radical stabilized by spiroconjugation of the unpaired electron over the group 13 element centre. The synthesized paramagnetic complex was characterized by EPR spectroscopy and computational chemistry.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-07-31 | Chemical Communications |