Determination of Cl/C and Br/C ratios in pure organic solids using laser-induced plasma spectroscopy in near vacuum ultraviolet

6533b821fe1ef96bd127c10c

RESEARCH PRODUCT

Determination of Cl/C and Br/C ratios in pure organic solids using laser-induced plasma spectroscopy in near vacuum ultraviolet

Jouko Korppi-tommola Saara Kaski Heikki Häkkänen

subject

Bromine Analytical chemistry Halide chemistry.chemical_element Astrophysics::Cosmology and Extragalactic Astrophysics Laser Analytical Chemistry law.invention chemistry law Halogen Chlorine Atomic ratio Emission spectrum Carbon Astrophysics::Galaxy Astrophysics Spectroscopy

description

Several solid organic compounds containing bromine and chlorine were analyzed with laser-induced plasma spectroscopy. Emission lines were detected in the near vacuum ultraviolet spectral region by using a gas-purged spectrograph and an intensified charge-coupled device detector. The performance of this setup in the determination of the halides in the organic samples was evaluated. Carbon emission lines in the near vacuum ultraviolet were used as internal standards for the measurement of chlorine and bromine. Linear correlation was found between the carbon and halogen emission signal ratio and the corresponding atomic ratio of the compound.

year	journal	country	edition	language
2004-01-01	J. Anal. At. Spectrom.

https://doi.org/10.1039/b315410f

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