6533b821fe1ef96bd127c117
RESEARCH PRODUCT
Quantum dynamics of 16O in collision with ortho- and para-17O17O
Pascal HonvaultGrégoire Guillonsubject
010304 chemical physicsChemistryQuantum dynamicsGeneral Physics and AstronomyObservable010402 general chemistryCollision01 natural sciences0104 chemical sciencesReaction rate constant0103 physical sciencesKinetic isotope effectPhysical chemistryPhysical and Theoretical ChemistryAtomic physicsQuantumdescription
Abstract We report full quantum dynamical observables, such as integral and differential cross sections and rate constants, for the 16 O + 17 O 17 O reactive collision process. We particularly emphasize the effect coming from the nonzero nuclear spin of 17 O, leading to two nuclear spin isomers of 34 O 2 , ortho- and para- 34 O 2 which can be studied independently and behave differently. A comparison with the 16 O + 18 O 18 O collision is given. We find that processes involving 17 O 17 O are always faster than with 18 O 18 O.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-12-01 | Chemical Physics Letters |