6533b822fe1ef96bd127ca73
RESEARCH PRODUCT
A self-assembled tetrameric water cluster stabilized by the hexachlororhenate(IV) anion and diprotonated 2,2′-biimidazole: X-ray structure and magnetic properties
Francesc LloretMiguel JulveG. De MunnoDonatella ArmentanoJosé Martínez-lilloJosé Martínez-lilloJuan FausNadia Marinosubject
CrystallographyFerromagnetismChemistryX-rayGeneral Materials ScienceGeneral ChemistryWater clusterCondensed Matter PhysicsIonSelf assembleddescription
A self-assembled tetrameric water cluster stabilized by [ReCl6]2− anions and [H4biim]2+ cations occurs in the new compound [H4biim][ReCl6]·4H2O, which exhibits a weak ferromagnetic coupling between the Re(IV) centers through an unusual ReIV–Cl⋯(H2O)⋯Cl–ReIV pathway.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2008-01-01 | CrystEngComm |