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RESEARCH PRODUCT
Modular approach to obtaining organic glasses from low-molecular weight dyes using 1,1,1-triphenylpentane auxiliary groups: Nonlinear optical properties
Valdis KokarsAndrejs TokmakovsMartins RutkisKaspars TraskovskisKristīne Lazdovičasubject
Materials scienceProcess Chemistry and TechnologyGeneral Chemical EngineeringSecond-harmonic generationNonlinear opticsCorona polinglaw.inventionAmorphous solidchemistry.chemical_compoundAzobenzenechemistryChemical engineeringlawOrganic chemistryThin filmCrystallizationGlass transitiondescription
Abstract A new modular synthetic approach to obtain organic glasses from low-molecular weight azobenzenes and stilbenes has been accomplished using 1,1,1-triphenylpentane crystallization preventing auxiliary groups. Six new structures show excellent solubility in non-polar solvents and thin films with good optical qualities have been obtained using a spin-coating technique. The glass transition temperatures of the new amorphous materials were in the range of 73–108 °C. The nonlinear optical activity in thin amorphous films was measured after a corona poling procedure.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-12-01 | Dyes and Pigments |