6533b822fe1ef96bd127ce81

RESEARCH PRODUCT

Self-Assembly of 1D/2D Hybrid Nanostructures Consisting of a Cd(II) Coordination Polymer and NiAl-Layered Double Hydroxides

Gonzalo AbellánJosé Luis García FierroAntonio RiberaPilar Amo-ochoaEugenio CoronadoFélix Zamora

subject

Materials sciencePolymers and PlasticsCoordination polymerLayered double hydroxidesOrganic chemistryNanotechnology02 engineering and technologyengineering.material010402 general chemistry01 natural sciencesArticleNanomaterialslcsh:QD241-441chemistry.chemical_compoundQD241-441lcsh:Organic chemistryMagnetic propertieshybrid materialslayered compoundshybrid materials; layered double hydroxides; coordination polymers; magnetic properties; layered compoundsLayered double hydroxidesGeneral ChemistryQuímica021001 nanoscience & nanotechnologylayered double hydroxidesExfoliation joint0104 chemical sciences3. Good healthCoordination polymerscoordination polymersLayered compoundschemistryHybrid systemengineeringHydroxideSelf-assemblyHybrid materialsmagnetic properties0210 nano-technologyHybrid material

description

The preparation and characterization of a novel hybrid material based on the combination of a 2D-layered double hydroxide (LDH) nanosheets and a 1D-coordination polymer (1D-CP) has been achieved through a simple mixture of suspensions of both building blocks via an exfoliation/restacking approach. The hybrid material has been thoroughly characterized demonstrating that the 1D-CP moieties are intercalated as well as adsorbed on the surface of the LDH, giving rise to a layered assembly with the coexistence of the functionalities of their initial constituents. This hybrid represents the first example of the assembly of 1D/2D nanomaterials combining LDH with CP and opens the door for a plethora of different functional hybrid systems.

10.3390/polym8010005http://europepmc.org/articles/PMC6432570