6533b822fe1ef96bd127d4e4

RESEARCH PRODUCT

Ferromagnetic coupling through a carbonate bridge in the copper (II) chain [Cu(CO3)(4-apy)2] · H2O (4-apy = 4-aminopyridine)

Oscar CastilloAntonio LuqueJon SertuchaMiguel JulvePascual RománFrancesc Lloret

subject

Aqueous solutionInorganic chemistrychemistry.chemical_elementCrystal structureCopperInorganic ChemistryCoupling (electronics)Crystallographychemistry.chemical_compoundchemistryFerromagnetismBromideMaterials ChemistryCarbonateCupratePhysical and Theoretical Chemistry

description

Abstract Atmospheric CO2 fixation by aqueous solutions containing copper(II) bromide and 4-aminopyridine (4-apy) yields the first carbonatobridged copper(II) chain of formula [Cu(CO3)(4-apy)2] · H2O that exhibits an intrachain ferromagnetic coupling.

https://doi.org/10.1016/s1387-7003(98)00134-8