6533b822fe1ef96bd127d5bf

RESEARCH PRODUCT

Accurate spectroscopic constants of nitrogen determined from stimulated Raman spectra of the fundamental and first hot bands

R. ChauxHubert BergerR. Saint-loupGuy MillotA. TabyaouiBruno Lavorel

subject

SpectrometerAtmospheric pressureChemistryAnalytical chemistryHot bandSpectral linesymbols.namesakesymbolsGeneral Materials ScienceCoherent anti-Stokes Raman spectroscopyRotational spectroscopyRaman spectroscopySpectroscopyRaman scattering

description

Nitrogen spectra of the Q-branch of the fundamental and the first hot bands were recorde with a high-resolution stimulated Raman spectrometer at atmospheric pressure and ca. 1300 K. The absolute frequencies of the Raman lines were measured with high accuracy, leading to a refinement of spectroscopic constants. A temperature estimation was also performed from the Raman intensities.

https://doi.org/10.1002/jrs.1250211208