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RESEARCH PRODUCT
Do fluorescence and transient absorption probe the same intramolecular charge transfer state of 4-(dimethylamino)benzonitrile?
Luis Serrano-andrésTakashige FujiwaraPedro B. CotoEdward C. LimThomas Gustavssonsubject
Time Factorstime resolved spectraGeneral Physics and Astronomyvisible spectra010402 general chemistryPhotochemistry01 natural sciencesTime resolved spectraSpectral lineFluorescencechemistry.chemical_compoundspectrochemical analysisOrganic compoundsUltrafast laser spectroscopyNitrilesCharge exchangePhysical and Theoretical ChemistryVisible spectra:FÍSICA::Química física [UNESCO]Fluorescent DyesSpectrochemical analysis010405 organic chemistryChemistrycharge exchangeFluorescenceUNESCO::FÍSICA::Química física0104 chemical sciences3. Good health[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryBenzonitrileIntramolecular forceCharge exchange ; Fluorescence ; Organic compounds ; Spectrochemical analysis ; Time resolved spectra ; Visible spectraAbsorption (chemistry)Time-resolved spectroscopyLuminescenceorganic compoundsdescription
International audience; We present here the results of time-resolved absorption and emission experiments for 4-(dimethylamino)benzonitrile in solution, which suggest that the fluorescent intramolecular charge transfer (ICT) state may differ from the twisted ICT (TICT) state observed in transient absorption.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2009-01-01 | The Journal of chemical physics |