6533b822fe1ef96bd127daa4
RESEARCH PRODUCT
A σ-Donor with a Planar Six-π-Electron B2N2C2 Framework: Anionic N-Heterocyclic Carbene or Heterocyclic Terphenyl Anion?
Taryn ForsterKelly KrahulicHeikki TuononenRobert McdonaldMasood ParvezRoland Roeslersubject
N-heterosykliset karbeenitN-heterocyclic carbenesterphenylsterfenyylitdescription
NB! The anionic ligand 2 was synthesized through deprotonation of a planar, formally zwitterionic diazadiborine precursor, isolated as a lithium salt, and structurally characterized. According to experimental evidence and theoretical calculations, 2 can be considered as an intermediate between two classical classes of ligands: N-heterocyclic carbenes 1 and terphenyls 3. peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2006-01-01 |