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RESEARCH PRODUCT

Breaking the Nd3+-sensitized upconversion nanoparticles myth about the need of onion-layered structures

María González-béjarRaul ArenalJuan Ferrera-gonzálezLaura Francés-sorianoJulia Pérez-prietoNestor Estebanez

subject

Materials scienceNanotechnology02 engineering and technologyCrystal structure010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesPhoton upconversion0104 chemical sciencesUpconversion nanoparticlesCucurbiturilGeneral Materials Science0210 nano-technologyLayer (electronics)

description

Up to now, most strategies to build efficient 800 nm-light responsive upconversion nanoparticles (UCNPs) have included onion-layered structures, in which Nd3+ is confined within the inorganic crystal structure of at least one layer. We report here an easy room-temperature modular preparation of core-shell UCNPs consisting of NaYF4:Yb,Er(Tm)/NaYF4 (UCCS) with Nd3+ anchored at the organic capping by using cucurbituril[7] (CB[7]) as an adhesive. Strikingly, excitation at 800 nm effectively triggers the upconversion emission of UCCS@CB[7]@Nd nanohybrids.

https://doi.org/10.1039/c8nr00871j