6533b823fe1ef96bd127ee22
RESEARCH PRODUCT
Diethyl (1-benzyl-4-phenyl-3-trifluoromethyl-1H-pyrrol-2-yl)phosphonate
Piotr M. ZagórskiDariusz CalBartosz ZarychtaKrzysztof EjsmontAnna Jezuitasubject
crystal structurefluorinated heterocycles010405 organic chemistryHydrogen bondChemistryTorsion (mechanics)Crystal structureDihedral angle010403 inorganic & nuclear chemistry01 natural sciences0104 chemical scienceschemistry.chemical_compoundCrystallographyphosphonyl grouplcsh:QD901-999lcsh:CrystallographyEthyl phosphatePyrroledescription
In the title compound, C22H23F3NO3P, the dihedral angles between the pyrrole ring and the benzyl and phenyl rings are 81.38 (7) and 46.21 (8)°, respectively. The ethyl phosphate groups present with P—O—C—C torsion angles of −178.47 (10) and 106.72 (16)°, and an intramolecular C—H...O hydrogen bond occurs. In the extended structure, molecules are linked by C—H...O and C—H...F hydrogen bonds to generate [001] chains.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-01-01 | IUCrData |