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RESEARCH PRODUCT

A novel oxovanadate structural type – Synthesis, single crystal structure and magnetic properties of a mixed-valence polyoxovanadate formed by {V17O40(Cl)} and {V15O36(Cl)} clusters

Bao-xia DongSamia BenmansourCarlos J. Gómez-garcíaJun PengJian-fang Ma

subject

Inorganic ChemistryCrystallographyMagnetic measurementsThermogravimetric analysisValence (chemistry)X-ray photoelectron spectroscopyStructural typeChemistryRedox titrationMaterials ChemistryPhysical and Theoretical ChemistrySingle crystalHydrothermal circulation

description

Abstract A novel polyoxovanadate structural type, with an average nuclearity of V16, formed by a mixture of two different polyoxovananadates: {V15O36(Cl)} and{V17O40(Cl)} has been synthesized and characterized. The title compound, formulated as [Ni(phen)3]2{[V15O36(Cl)]0.5[V17O40(Cl)]0.5} · H2O (1) (phen = 1,10′-phenanthroline), presents two different polyoxovanadate architectures: {V15O36(Cl)} and {V17O40(Cl)}, with the last one representing a new framework type in polyoxovanadate chemistry. Here, we present the synthesis of this novel polyoxovanadate under hydrothermal conditions and its characterization by IR and XPS spectroscopies, elemental and thermogravimetric analysis, redox titration, magnetic measurements and single-crystal X-ray diffraction.

yearjournalcountryeditionlanguage
2007-04-01Polyhedron
https://doi.org/10.1016/j.poly.2006.10.050